• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The present invention relates to a device (10) and a method for sterilizing thermoplastic containers by means of a pulsed electron beam (F) which is formed of a succession of pulses each having a duration (d) of emission which is less than 100 ns and an intensity (i) which is greater than 1 kA to sterilize, through a wall (18) of the container, at least the inside (20) of said container (12).
    公开号:FR3031903A1
    申请号:FR1550638
    申请日:2015-01-28
    公开日:2016-07-29
    发明作者:Cedric Bianchini；Guy Feuilloley
    申请人:Sidel Participations SAS；
    IPC主号:
    专利说明:

    [0001] The present invention relates to a device and method for sterilizing thermoplastic containers by means of a pulsed electron beam. The present invention relates to a device and a method for sterilizing thermoplastic containers by means of a pulsed electron beam. . Various sterilization processes are known from the state of the art to sterilize at least the interior of a preform and / or a thermoplastic container. The manufacture of a container of thermoplastic material is obtained from a hot preform, generally previously thermally conditioned in a furnace of a container manufacturing plant before being introduced into a mold to be converted by blow molding. means 15 of at least one fluid under pressure, with or without stretching. Different types of containers (bottles, flasks, pots, etc.) are thus produced, forming hollow bodies which are in particular, but not exclusively, intended to be used for the packaging of products in the food industry. In the field of the manufacture of containers for the food industry, efforts are being made by all means to reduce the risk of microbiological contamination of the containers by pathogenic agents, namely micro-organisms. This is the reason why the Applicant has already proposed to implement various actions to eliminate pathogens, such as germs (bacteria, molds, etc.), which are likely to affect the product contained in such containers. The documents of the state of the art cited below and to which reference will be made for further details, illustrate by way of non-limiting examples such actions. In particular, it is possible to distinguish, on the one hand, the actions aimed at destroying the microorganisms to sterilize at least the inside of the container and, on the other hand, the actions aimed more generally at preventing the containers from being contaminated by such containers. microorganisms. Document FR-2,915,127 describes a container manufacturing installation comprising a protective enclosure delimiting an area inside which there is arranged a blower-type container molding machine which is fed by means of preform transfer means thermally conditioned in an oven.
    [0002] According to the teachings of this document, the installation comprises a system for blowing filtered air inside the enclosure in order to establish in particular an overpressure so as to limit the risks of contamination of both the preforms leaving the oven and manufactured containers.
    [0003] The document WO-03/084818 for example describes a radiation decontamination treatment of the preform neck by ultraviolet (UV) type radiation before the preforms are introduced into the oven. Document EP-2.094.312 describes, for example, irradiation treatment with ultraviolet (UV) radiation implemented in a particular manner in an oven for decontaminating at least the external surface of the preform during thermal conditioning. Document WO-2006/136498 describes, for example, a decontamination treatment of a preform consisting in depositing by condensation a substantially uniform vapor film of a sterilizing agent on the inner wall of the preform. The decontamination of the preform is carried out by means of a treatment device intervening before the introduction of the preform into the furnace. Such a treatment is intended to destroy the pathogens or microorganisms to decontaminate at least the inside of the preform corresponding to the so-called "food" internal surface of the container to be made, that is to say the one that will be , after filling, in direct contact with the product. It is recalled that the amount of microorganisms is countable by counting after washing, filtration and cultivation operations. A logarithmic reduction of the number of microorganisms is thus determined, for example, of the order of 3Log (or even 3D) equivalent to 1000 units (103). Such a "chemical way" condensation decontamination treatment is satisfactory since decontamination steps up to 6Log are obtained. However, alternative solutions are being sought which make it possible not to use a sterilizing agent, such as hydrogen peroxide (H 2 O 2), in order to find solutions that are more environmentally friendly, but without, however, sacrificing to the result obtained for the decontamination. The use of sterilizing agent, such as hydrogen peroxide, requires the implementation of a set of 20 particular means to meet in particular regulatory obligations to protect exposed personnel and more generally the environment (management effluents, etc.), which contributes to increase operating costs. Of course, the various examples of the aforementioned actions are advantageously capable of being implemented in combination in the same installation to treat the different surfaces of a preform and more generally to drastically reduce the risk of contamination. Thermoplastic containers, such as PET (Polyethylene Terephthalate), which are the subject of this invention include, but are not limited to, bottles.
    [0004] Such a hollow container is delimited as a whole by a wall and has a collar delimiting radially an opening and extending by a body axially closed by a bottom. For the sterilization of the interior of this type of thermoplastic containers 5, one of the problems encountered is the limited accessibility to the inner surface of the container that the neck opening, which generally has a small diameter, offers. One of the alternatives is to use an electron beam ionizing radiation that is used to irradiate the surface to be sterilized. The arrangement of an emitter of the electron beam outside the container makes it possible to overcome this problem of limited accessibility, the electrons of the beam emitted by the emitter pass from the outside towards the radially, the wall of the body and the neck of said container for irradiating the interior of the container to be sterilized. However, when the continuous-beam electron beam used is emitted by a so-called "high energy" transmitter, that is to say generally with an energy greater than 500 KeV and by As an example of the MeV order, it can be seen that the electrons of such a continuous beam cause modifications of the thermoplastic material with which said electrons interact by passing through the wall of the container. However, such modifications alter the properties of the thermoplastic material of the container and are likely to compromise the subsequent use as packaging. In order to limit the interactions between the continuous electron beam and the thermoplastic material, the use of a low energy emitter (less than 500 KeV) has been envisaged. However, the lower energy level of the electrons in the continuous beam results in insufficient sterilization from the moment the beam has to pass through the wall of the container, both body and neck, to irradiate the inner surface thereof. The desired degree of sterilization can thus only be achieved by increasing the irradiation time to compensate for the low penetration of the low-energy continuous electron beam, but the times required for the treatment of a container are then incompatible with the rates. Manufacturing. In addition, problems of interactions between the continuous electron beam and the thermoplastic material remain and the deterioration of the thermoplastic material is all the more important as the irradiation time is long. According to a known solution of US Pat. No. 8,728,393, part of the problems can be solved by introducing the continuous electron beam through the opening of the neck, directly inside, without passing through the wall. Given the neck diameters of a preform (or container), however, the emitter remains outside the preform and the continuous electron beam must be brought, guided to the inside for to be able to carry out the irradiation. Such a solution is particularly complex to implement to be exploited industrially and to achieve irradiation of the entire internal surface, the only way to ensure reliable sterilization.
    [0005] By irradiating the interior of the preform according to US Pat. No. 8,728,393 and not to that of the container obtained from such a preform, there is also a risk of contamination of the preform or the container afterwards. to sterilization so that, at the very least, drastic preventive measures must then be implemented to limit any risk of contamination subsequent to irradiation sterilization.
    [0006] When means for guiding the electron beam are introduced axially inside the preform to carry out the sterilization, there is a risk of contamination of the interior of the preform, container in the making.
    [0007] Indeed, such guide means are not sterile and may be the vector of contamination by microorganisms, in particular contamination of the rim that is to say the circumferential edge of the neck defining the opening of the preform or container.
    [0008] Although essentially the known solutions of the state of the art use a continuous-type electron beam, FR-2.861.215 also discloses the use of a low-energy electron beam, pulsed type, for the sterilization of packaging such as bottles.
    [0009] As described in this document, the pulsed-type electron beam is obtained in particular by not permanently applying, but only for a given time, the voltage causing the electron acceleration of the beam. With an emitter such as the electron gun with focusing anode of document FR-2.861.215, it is indicated by way of example that the voltage is applied for 2 μs (microsecond) with a frequency of 500 Hz, ie a transmission all the 2 ms (millisecond), and a current with an intensity of 10 A.
    [0010] The use of an electron gun with a focusing anode according to document FR-2.861.215 or a similar emitter, however, does not give satisfaction in sterilizing the inside of containers made of thermoplastic material. Indeed, the treatment time necessary to irradiate with a sufficient quantity of electrons the surface to be sterilized, that is to say to obtain a lethal dose, is too important and is therefore not compatible with the rates Currently, in the case of PET bottles, for example, they reach 50,000 to 60,000 bottles per hour. The problems of deterioration of the thermoplastic material also remain with such a pulsed electron beam which makes it impossible to envisage any industrial application thereof. The various alternative solutions known from the state of the art and which have just been described are therefore not satisfactory for sterilizing at least the inside of thermoplastic containers, in particular PET bottles. The object of the present invention is in particular to solve at least some of the drawbacks of the state of the art and to propose a solution allowing, without degrading the constituent material, to sterilize reliably and rapidly the interior of the invention. a container of thermoplastic material. For this purpose, the invention provides a method for sterilizing containers of thermoplastic material comprising at least one step of irradiating a container from the outside by means of a pulsed electron beam which is formed from a succession of pulses each having an emission duration that is less than 100 ns and an intensity that is greater than 1 kA to sterilize the interior of said container through a wall of the container. Advantageously, the pulsed-type electron beam according to the invention is discrete, formed by a succession of pulses having a very high intensity of the order of one kilo-amperes (kA) and with a particularly short duration of emission of the order of nanoseconds (ns). By virtue of a pulsed electron beam having an emission time of less than 100 ns and an intensity of more than 1 kA, the sterilization of the interior of the container is achieved with not only a treatment time. compatible with the production rates, but still 3031903 8 and above without the interactions between the pulsed beam electrons and the thermoplastic material compromise the subsequent use of the sterilized container. By comparison with a pulsed electron beam according to document FR-2 861 215, the duration of emission of a pulse is very short since this duration is less than 100 ns in the case of the invention, for example a few nanoseconds, while it is expressed in microseconds (ps) with a transmitter like the electron gun with focusing anode according to this document.
    [0011] The pulsed electron beam according to the invention is for example obtained by means of an explosive emission of electrons, still sometimes designated by the acronym E.E.E for "Explosive Electron Emission" in English. The short duration of a nanosecond pulsed electron beam emission coupled with high pulse intensity in kilo-amperes limits the electron interactions with the thermoplastic while having irradiation for effective sterilization. The results obtained with the invention are particularly surprising, especially since those obtained so far, both with a continuous electron beam, and with a pulsed electron beam (such as that produced with an electron gun according to FIG. FR-2,861,215) deterred a person skilled in the art from continuing the sterilization of the interior of a container by means of an electron beam. For those skilled in the art, it is therefore not possible, on the one hand, to sterilize rapidly through its wall the inside of a container by means of an electron beam and, on the other hand, to do without altering the thermoplastic material. The use of an electron beam therefore goes against the prejudices of the skilled person. Indeed, for the skilled person, it is not possible with an electron beam to sterilize the inside of a container by irradiating it from the outside through the wall without encountering any alterations. inhibiting the thermoplastic material by the electron beam, as well as irradiation times to obtain a lethal dose which are incompatible with an industrial application. Advantageously, said pulsed electron beam is emitted with, between two successive pulses, a time interval (T) which is greater than 3 ms, for example equal to 10 ms.
    [0012] Such a time interval advantageously participates in limiting the interactions of the electrons of the beam with the thermoplastic material. In the absence of a substantial time interval with respect to the duration of emission of a pulse, the irradiation obtained with the pulsed electron beam finally differs little from that obtained with a continuous electron beam. In comparison with the irradiations carried out with the solutions of the state of the art, the microorganisms are surprisingly destroyed with greater efficiency by a pulsed electron beam according to the teachings of the invention. In particular, the destruction of the micro-organisms is more efficient when the irradiation is carried out with a succession of very short pulses, of high intensity (i) and advantageously a time interval (T) between two successive pulses determined. Advantageously, the pulsed electron beam irradiates the microorganisms by repeatedly alternating moments of "stress" micro-organisms during which the last 30 are irradiated with a high intensity, with a moment of respite between two "stress" "Successive.
    [0013] Advantageously, said pulsed electron beam has an energy, called low energy, which is less than 500 KeV, preferably greater than 400 KeV. Advantageously, the method comprises a step of axially introducing a reflector inside the container to be sterilized. Preferably, said step of introducing the reflector is performed prior to the irradiation step. As a variant, the step of introducing the reflector is carried out during the irradiation step, in particular so as to reduce the total duration of irradiation treatment to sterilize a container. Advantageously, the reflector is sterilized by the pulsed electron beam according to the invention, the external surface of the reflector being at least irradiated by the electrons of the beam 15 when the reflector extends axially inside the container. Advantageously, the implementation of such a sterilization process is compatible with the production rates of containers and therefore capable of receiving industrial application by integrating a sterilization device into a container manufacturing installation such as PET bottles. Advantageously, the sterilization of the container according to the process of the invention is carried out by irradiating an empty container, preferably just before filling it.
    [0014] In comparison with a chemical preform sterilization method according to the aforementioned WO-2006/136498, the invention makes it possible to greatly simplify the design of a container manufacturing facility and reduce its operating costs. .
    [0015] The sterilization of the final container (and not of the preform) advantageously makes it possible to dispense with many of the means previously used in a container manufacturing installation from a preform, the microorganisms present being destroyed during the irradiation of the container by means of the pulsed electron beam according to the invention. Indeed, by sterilizing the container and still by comparison, it is in particular no longer necessary to use specific means (such as insufflation systems, etc.) to preserve the sterility of a preform after its treatment. that is to say during its thermal conditioning, blow-molding or stretch-blow molding in a container until the filling and closing of the container. Advantageously, the sterilization process according to the invention makes it possible to sterilize both the inside and the outside of the container. The devices for treating the preforms by irradiation with UV radiation are, for example, likely to be eliminated in the same way as the insufflation systems and more generally the air filtration systems involved in obtaining a clean manufacturing environment. Preferably, the sterilization process according to the invention is carried out in the container manufacturing plant between the molding unit (or blower) and the next unit, such as a filling unit. The invention also proposes a sterilization device comprising at least one emitter of a pulsed electron beam and an associated reflector axially inserted at least partly inside said container for selectively reflecting all or part of said electron beam. pulsed emitted by said emitter from the outside, through a wall of the container, to irradiate said container to sterilize at least the interior of said container.
    [0016] Advantageously, said sterilization device is intended for implementing the method described above. According to other characteristics of the sterilization device according to the invention: - the reflector is mounted axially movable relative to the container, between at least a first position in which the reflector extends outside the container and a second a position in which the reflector, introduced through an opening 5 defined by a neck of the container, extends axially at least partly inside said container; the reflector has a reflectance which varies axially, said reflector comprising at least a first portion having a reflectance and a second portion having a reflectance which is less than the reflectance of the first portion; the first part of the reflector having the reflectance and the second part of the reflector having the reflectance are respectively made of different materials; The reflector comprises at least one specific part having at least one reflection surface which does not extend in an axial plane; said at least one specific reflection part is located at the free axial end of the reflector; Said at least one specific reflection portion is formed by a radially extending ring projecting outwardly; said at least one specific reflection part comprises at least one frustoconical reflection surface; The reflector comprises at least one part having a determined electrical charge, said charge being negative to obtain an electron repulsion effect or positive to obtain an electron absorption effect; the device comprises means for rotating the container to rotate said container relative to the emitter of the pulsed electron beam. Other features and advantages of the invention will appear on reading the description which follows for the understanding of which reference will be made to the appended drawings in which: FIG. 1 is a graphical representation which represents on the ordinate the intensity (i) expressed in kilo-amperes 5 (kA) and in abscissa the time expressed in milliseconds (ms) and which respectively illustrates a beam Fo of continuous electrons and a pulsed electron beam F according to the invention which is formed by a series of pulses characterized by their emission duration (t), their intensity (i) and the pulse emission frequency with an interval (T) between two pulses; FIG. 2 is a graph which represents, on the ordinate, the dose (D) of received electrons expressed in kilo-Gray (kGy) and on the abscissa the thickness (E) expressed in micrometer (μm) of the wall of a container. in PET and which illustrates the dose deposited on the outer surface of the container and through the wall to obtain a determined lethal dose on the inner surface of the container, the curve C1 corresponding to an irradiation of the container with a continuous electron beam, curve C2 with a pulsed electron beam having an energy level of 250 KeV and curve C3 with a pulsed electron beam having an energy level of 430 KeV; FIG. 3 is a side view which represents an exemplary embodiment of a sterilization device according to the invention and which illustrates the irradiation of a container by the sterilization device comprising a transmitter of a beam of pulsed electrons emitted radially from the outside and which is associated with a reflector axially introduced into the container; FIG. 4 is a top view showing the container and the sterilization device according to FIG. 3 and which illustrates the sterilization of the container by the bundle in accordance with the invention. The method for sterilizing thermoplastic containers according to the invention comprises at least one irradiation step of irradiating a container from the outside by means of a pulsed electron beam (F) which is formed of a succession of pulses each having a duration (d) of emission which is less than 100 ns and an intensity (i) which is greater than 1 kA to sterilize the inside of said container through a wall of the container. Advantageously, said pulsed electron beam (F) is emitted with, between two successive pulses, a time interval (T) which is greater than 3 ms.
    [0017] Advantageously, said pulsed electron beam (F) has a so-called low energy energy which is less than 500 KeV. Preferably, said pulsed electron beam (F) has an energy greater than 400 KeV for example of the order of 430 to 450 KeV. In a variant, said pulsed electron beam (F) has an energy, called low energy, of less than 500 KeV, which is for example equal to 250 KeV. FIG. 1 shows a pulsed electron beam (F) according to the invention which is formed by a series of pulses, the duration (t) of emission of each pulse being equal to 10 ns and with an intensity of 5 kA. Said pulsed electron beam (F) of FIG. 1 has an energy level of 250 KeV, a value of less than 500 KeV corresponding to a generally accepted threshold value between "low energy" and high energy. Preferably, said pulsed electron beam (F) shown in FIG. 1 is emitted with, between two successive pulses, a time interval (T) which is equal to 10 ms.
    [0018] For purposes of comparison, FIG. 1 also shows a continuous electron beam (Fo) (hatched) which differs in particular from the pulsed electron beam (F) due to the absence of a series of electrons. pulses between each of which the intensity (i) returns to a zero value. The continuous electron beam (Fo) represented has a 200 KeV energy, ie a low energy, and an intensity equal to 5 mA, the emission duration for irradiation sterilization being of the order of less a second. By comparison between these two types of electron beam, it is found that the continuous electron beam 10 requires a beam emission duration to irradiate which is longer and that for a smaller amount of electrons received. Indeed, the pulsed electron beam consisting of the repetition of a series of very short pulses makes it possible to irradiate the surface to be sterilized with a larger quantity of electrons, in particular because of the much higher intensity of each pulse of the pulsed electron beam with respect to the intensity of the continuous electron beam. The intensity of a pulse equal to 5 kA is very much higher than that of 5 mA of the continuous electron beam.
    [0019] By virtue of this intensity of the order of kA, the number of electrons of the pulsed electron beam (F) passing through the wall of the container to irradiate the microorganisms present inside the container will make it possible to sterilize both the the outside of the container, and that over its entire height is axially from the neck to the bottom. Irradiation obtained with a pulsed electron beam (F) is also effective on parts of the container having complex surfaces for example because of the "design" of the container.
    [0020] Thanks to a pulsed electron beam according to the invention, a lethal dose is applied to the inner surface of the container to be sterilized and this transmitting a lower energy to the thermoplastic material of the container through which the beam (F) 3031903 16 d pulsed electrons, which advantageously limits the risks of alterations of the material but without sacrificing sterilization efficiency. The irradiation of the microorganisms by a pulsed electron beam (F) 5 is more efficient because the microorganisms are more difficult to protect themselves from the repetition of the pulses having the characteristics of duration (t) and intensity (i). pulsed electron beam (F). Advantageously, the duration of treatment with a pulsed electron beam (F) is less than that which would be necessary with a continuous electron beam (Fo) to obtain irradiation with an equivalent amount of electrons. FIG. 2 is a graphical representation illustrating the dose (D) expressed in kilo-Gray (kGy) as a function of the thickness (E) in micrometer (μm) of the wall of a PET container, from the outer surface to the inside of the container to be sterilized. The dose (D) in kilo-Gray (kGy) corresponds to Joules per kg (kilogram), ie one energy per unit of volume, which corresponds to a cumulative dose illustrates the energy yielded by the 20 electrons and absorbed by the material. of the container. Curve C1 corresponds to irradiation with a continuous electron beam (Fo), curve C2 corresponds to irradiation with a pulsed electron beam (F1) having an energy level of 250 KeV and curve C3 corresponds to irradiation with a pulsed electron beam (F2) having an energy level of 430 KeV. The value of 250 μm corresponds to a typical value for a wall of a container such as a PET bottle. FIG. 2 shows the dose of radiation absorbed through a wall of 250 μm PET with the different beams (Fo), (F1) and (F2) to obtain inside the container a dose of at least one value. equal to 14 kGy.
    [0021] As illustrated in FIG. 2, the energy absorbed by the PET to obtain the desired lethal dose of at least 14 kGy at a depth of 250 μm is much lower when the electron beam is of the pulsed type. compared to a continuous electron beam (Fo), and by comparing the two pulsed-type beams the absorbed energy is even less with the energy beam (F2) of 430 KeV than with the beam (F1) of 250 KeV energy. A beam (F) such as the pulsed electron beam (F2) having an energy of 430 KeV provides a more even irradiation of the container through the wall, the outer surface and the inner surface. Advantageously, the energy absorbed by the PET is less with such a beam (F2) which reduces the risk of damage to the thermoplastic material. The greater the energy of the beam, the greater the amount of electrons passing through the wall of the vessel to irradiate the inner surface. A beam (F2) having an energy of 430 KeV allows, in comparison with the energy beam (F1) of 250 KeV, to reduce substantially the total irradiation time which is particularly advantageous for an implementation in a container manufacturing facility. Preferably, the beam (F) has an energy greater than 400 KeV. To further improve the irradiation and shorten the processing time, the invention proposes to associate with the transmitter a reflector intended to be introduced axially into the container through the opening of the neck so as to selectively reflect the beam. (F) pulsed electrons. Advantageously, the method comprises, prior to the irradiation step, a step of axially introducing a reflector inside the container to be sterilized.
    [0022] FIGS. 3 and 4 show an exemplary embodiment of a device 10 for sterilizing a container 12 intended for carrying out the sterilization process which has just been described.
    [0023] In the remainder of the description, the "axial" orientation with reference to the main axis of the container and the direction of displacement of the reflector as well as the "radial" orientation which is orthogonal to the "axial" orientation.
    [0024] The container sterilization device 10 comprises at least one emitter 14 of a pulsed electron beam (F) and an associated reflector 16. The reflector 16 is introduced axially at least partly inside said container 12 to selectively reflect all or part of said pulsed electron beam (F) emitted by said emitter 14 from the outside, radially through a wall 18 of the In order to facilitate the representation of the beam by diffuse nature (electron cloud), the beam (F) of electrons has been shown in the form of a radially oriented arrow, however such a representation However, it is in no way limiting and the beams of the beam (F) are not necessarily orthogonal to the axial direction. Irradiation of the container 12 is more particularly intended to sterilize the interior of the container, ie the inner surface 20 of the container which will subsequently be in contact with a product, in particular a liquid food such as water, milk, juice, etc. However, irradiation being effected from outside the container 12 and through the wall 18 will also sterilize the outer surface 22 so that the container 12 is sterilized as a whole by the pulsed electron beam (F). .
    [0025] The container 12 shown in FIGS. 3 and 4 is given solely by way of example, the container 12 comprises a cylindrical body 24 extending axially between a bottom 26 and a neck 28, said neck 28 defining an opening 30 radially. .
    [0026] The wall 18 has a given thickness (E) of thermoplastic material, for example PET, and the term "wall" must be understood in the broad sense for the entire container 12, axially from the bottom 26 to the neck 28 and the body 24. The reflector 16 is axially movable, relative to the container 12, between at least a first position (not shown) and a second position shown in Fig. 3. The first position corresponds to a position in which the reflector 16 extends outside the container 12, completely outside the container 12.
    [0027] The first position is in particular occupied by the reflector 16 after the sterilization of a container 12 and waiting for the sterilization of the next container 12. The second position corresponds to a position in which the reflector 16, introduced through the opening 30 delimited by the neck 28 of the container 12, extends axially at least partly inside said container 12. Preferably, the reflector 16 is associated with drive means, such as an actuator, which is controlled to move axially, along the arrow A shown in Figure 3, the reflector 16 relative to the container 12 occupying a fixed position. Alternatively, the reflector 16 could be fixed and the container 12 moved axially relative to the reflector 16 to introduce the latter inside the container 12.
    [0028] The reflector 16 is in the form of an axial rod having a maximum outer diameter which is smaller than the inner diameter of the neck of the container 12 so that it can be axially introduced into the interior of said container, preferably without contact. with the collar 28 in particular. Advantageously, the reflector 16 has a reflectance which varies axially according to the part of the reflector 16 5 considered. The reflector 16 comprises at least a first portion 32 having a reflectance R1 and a second portion 34 having a reflectance R2 which is smaller than the reflectance R1 of the first portion 32.
    [0029] Preferably, the second portion 34 of the reflector 16 having the reflectance R2 is located axially on the reflector 16 to be located at the neck 28 and / or the shoulder of the container 12 when the reflector 16 occupies said second position.
    [0030] Advantageously, said at least one second portion 34 of the reflector 16 having the lower reflectance R2 is determined according to the "design" of the container 12, the least reflective portion or portions such as the second portion 34 being located axially on the reflector 16 to be radially 20 opposite the portion or portions of the container 12 radially closer to the reflector 16 such that the shoulder of the container 12 extending below the neck 28. The reflector 16 is advantageously made of in whole or in part, in at least one material having a high relative mass, preferably greater than 180, such as tantalum (Ta), tungsten (W), platinum (Pt) or gold (Au). The first portion 32 of the reflector 16 having the reflectance R1 and the second portion 34 of the reflector 16 having the reflectance R2 are for example obtained by using different materials for each. As shown in FIGS. 3 and 4, the reflective outer surface of the reflector 16 is formed wholly or partly by a cylindrical surface which reflects with a given incidence the electrons of the beam F pulsively emitted by the emitter 14. radially through the wall 18 of the container 12. The pulsed electron beam F according to the invention arrives orthogonally to the cylindrical surface of the reflector 16 before being reflected with a given incidence towards the inner surface 20 of the container 12 to be sterilized . However, a container 12 such as a PET bottle generally has a particular "design" and thereby one or more zones, such as the specific waveform-specific area 36, not having a cylindrical surface which is extends axially parallel to that of the reflector 16 but having protruding portions and / or recessed. To improve the irradiation of such specific areas, the reflector 16 has at least one specific portion 38 so as to reflect the pulsed electron beam F in the direction of at least one associated specific area. Advantageously, said specific portion 38 of the reflector 16 comprises at least one reflection surface that does not extend in an axial plane.
    [0031] In the example, said at least one reflection surface is not parallel to the inner surface of the wall 18, nor orthogonal to the beam F of electrons radially transmitted through the wall 18 of the container 12 by said emitter 14. the exemplary embodiment, said specific portion 25 is constituted by at least one ring extending radially projecting from the rest of the reflector 16 and having in axial section a profile-shaped "V" lying. The specific ring-shaped portion 38 has an upper reflection surface 40 and a lower frustoconical reflection surface 42. Advantageously, the reflector 16 has another specific reflection portion 34 which is located at the free axial end of the reflector 16.
    [0032] Preferably, said other specific reflection portion 44 comprises at least one frustoconical reflection surface 46 intended to reflect the electron beam F towards the bottom 26, generally of petaloid shape.
    [0033] Advantageously, the reflector 16 comprises at least one part having a determined electrical charge, said charge being negative to obtain a repulsion effect of the electrons of the beam F or positive to obtain an absorption effect of said electrons.
    [0034] A variation of the reflectance according to the axial position of a given portion of the reflector relative to another is obtainable with portions having different electrical charges. Preferably, the reflector 16 is electrically connected to the ground or ground. Advantageously, the device 10 comprises means 48 for rotating the container 12 in order to drive it in rotation relative to the emitter 14 of the pulsed electron beam F.
    [0035] The sterilization device 10 which has just been described constitutes the sterilization station or one of the sterilization units of a thermoplastic container manufacturing plant 12 from hot preforms. Such a sterilization unit of containers 12 comprising at least one sterilization device 10 is arranged downstream of the molding unit in which the hot preforms, for example previously thermally conditioned in an oven, are converted into containers 12 by blowing or By stretch blow molding using at least one pressurized fluid Advantageously, the sterilization unit is arranged upstream of a container filling unit 12 that comprises the container manufacturing plant 12 made of thermoplastic material.
    [0036] An installation for manufacturing containers 12 of thermoplastic material of this type is known from the state of the art and reference is made for example to the document WO-99/03667, however given in a non-limiting manner. 5
    权利要求:
    Claims (10)
    [0001]
    REVENDICATIONS1. A process for sterilizing thermoplastic containers (12) having at least one irradiation step of irradiating a container (12) from the outside by means of a pulsed electron beam (F) which is formed pulse sequence each having a duration (d) of emission which is less than 100 ns and an intensity (i) which is greater than 1 kA to sterilize through a wall (18) of the container the inside (20) of said container (12).
    [0002]
    2. sterilization process according to claim 1, characterized in that said pulsed electron beam (F) is emitted with, between two successive pulses, a time interval (T) which is greater than 3 ms.
    [0003]
    3. Sterilization process according to claim 1 or 2, characterized in that said pulsed electron beam (F) has an energy, called low energy, which is less than 500 KeV.
    [0004]
    4. Sterilization process according to any one of the preceding claims, characterized in that the method comprises a step of axially introducing a reflector (16) inside the container (12) to be sterilized.
    [0005]
    Sterilization device (10) for carrying out the sterilization method according to any one of the preceding claims, characterized in that said sterilization device (10) comprises at least one emitter (14) of a beam ( F) pulsed electrons and an associated reflector (16) axially inserted at least partly inside said container (12) for selectively reflecting all or part of said pulsed electron beam (F) emitted by said emitter (14) from outside, through a wall (18) of the container, to irradiate said container (12) to sterilize at least the interior (20) of said container (12).
    [0006]
    6. sterilization device according to claim 5, characterized in that the reflector (16) is mounted axially movable, relative to the container (12), between at least a first position in which the reflector (16) extends to the outside of the container (12) and a second position in which the reflector (12), introduced by an opening (30) delimited by a neck (28) of the container, extends axially at least partly inside. said container (12).
    [0007]
    7. sterilization device according to claim 5 or 6, characterized in that the reflector (16) has a reflectance which varies axially, said reflector (16) having at least a first portion having a reflectance (R1) and a second part having a reflectance (R2) which is less than the reflectance (R1) of the first part.
    [0008]
    8. sterilization device according to claim 7, characterized in that the first part of the reflector (16) having the reflectance (R1) and the second part of the reflector (16) having the reflectance (R2) are respectively made of materials different.
    [0009]
    9. Sterilization device according to any one of claims 5 to 8, characterized in that the reflector (16) comprises at least a specific portion (38, 44) having at least one surface (40, 42, 46) of reflection that does not extend in an axial plane.
    [0010]
    10. A sterilization device according to any one of claims 5 to 9, characterized in that the reflector (16) comprises at least a portion having a determined electrical charge 25, said charge being negative to obtain a repulsion effect of the electrons or positive to obtain an effect of absorption of the electrons.
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    同族专利:
    公开号 | 公开日
    EP3250241B1|2021-06-30|
    WO2016120544A1|2016-08-04|
    US20180015191A1|2018-01-18|
    CN107206115A|2017-09-26|
    CN107206115B|2021-04-02|
    JP2018505101A|2018-02-22|
    FR3031903B1|2017-01-13|
    EP3250241A1|2017-12-06|
    JP6810046B2|2021-01-06|
    引用文献:
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    FR2140393A1|1971-06-07|1973-01-19|Energy Sciences Inc|
    US20030164285A1|2002-03-04|2003-09-04|Steris Inc.|Mobile radiant energy sterilizer|
    US8728393B2|2011-12-08|2014-05-20|Krones Ag|Apparatus and method of sterilizing inner walls of containers with a reflector apparatus|
    JP2002173114A|2000-12-07|2002-06-18|Ishikawajima Harima Heavy Ind Co Ltd|Method for sterilizing vessel|
    US20030174810A1|2002-03-12|2003-09-18|Steris Inc.|Method and apparatus for destroying microbial contamination of mail|
    FR2838076B1|2002-04-04|2005-03-04|Sidel Sa|METHOD AND INSTALLATION FOR DECONTAMINATION OF PREFORMS|
    FR2861215B1|2003-10-20|2006-05-19|Calhene|ELECTRON GUN WITH FOCUSING ANODE, FORMING A WINDOW OF THIS CANON, APPLICATION TO IRRADIATION AND STERILIZATION|
    FR2887525B1|2005-06-24|2007-09-07|Sidel Sas|INSTALLATION PRODUCING STERILE BOTTLES BY BLOWING FROM STERILIZED PREFORMS|
    FR2907684B1|2006-10-26|2009-12-04|Sidel Participations|METHOD OF STERILIZING A PREFORM, INSTALLATION AND OVEN FOR MANUFACTURING STERILE CONTAINERS ACCORDING TO THIS PROCESS|
    FR2915127B1|2007-04-20|2012-10-12|Sidel Participations|INSTALLATION FOR THE MANUFACTURE OF CONTAINERS COMPRISING A PROTECTION ENCLOSURE EQUIPPED WITH A SYSTEM OF AIR FILTER INSUFFLATION|
    KR101621830B1|2009-01-22|2016-05-17|시부야 코교 가부시키가이샤|Apparatus and method for sterilizing vessel with electron beam|FR3082749B1|2018-06-22|2020-05-29|Sidel Participations|METHOD OF DECONTAMINATION USING ELECTRON BEAMS OF A BOTTOM CONTAINER IN THERMOPLASTIC MATERIAL|
    WO2020094994A1|2018-11-09|2020-05-14|Sidel Participations|Method and device for sterilizing, by irradiation, a container made of thermoplastic material|
    FR3088203A1|2018-11-09|2020-05-15|Sidel Participations|METHOD AND DEVICE FOR STERILIZATION BY IRRADIATION OF A CONTAINER OF THERMOPLASTIC MATERIAL|
    FR3088202B1|2018-11-09|2020-10-16|Sidel Participations|TREATMENT PROCESS FOR THE STERILIZATION BY IRRADIATION OF CONTAINERS OF THERMOPLASTIC MATERIAL|
    法律状态:
    2015-12-22| PLFP| Fee payment|Year of fee payment: 2 |
    2016-07-29| PLSC| Publication of the preliminary search report|Effective date: 20160729 |
    2016-12-21| PLFP| Fee payment|Year of fee payment: 3 |
    2017-12-21| PLFP| Fee payment|Year of fee payment: 4 |
    2018-12-20| PLFP| Fee payment|Year of fee payment: 5 |
    2019-12-19| PLFP| Fee payment|Year of fee payment: 6 |
    2020-12-17| PLFP| Fee payment|Year of fee payment: 7 |
    2021-12-15| PLFP| Fee payment|Year of fee payment: 8 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1550638A|FR3031903B1|2015-01-28|2015-01-28|DEVICE AND METHOD FOR STERILIZING THERMOPLASTIC CONTAINERS USING A PULSE ELECTRON BEAM|FR1550638A| FR3031903B1|2015-01-28|2015-01-28|DEVICE AND METHOD FOR STERILIZING THERMOPLASTIC CONTAINERS USING A PULSE ELECTRON BEAM|
    EP16703585.6A| EP3250241B1|2015-01-28|2016-01-20|Device and method for sterilizing thermoplastic containers using a pulsed electron beam and a mobile reflector|
    US15/546,966| US20180015191A1|2015-01-28|2016-01-20|Device and method for sterilizing thermoplastic containers using a pulsed electron beam and a mobile reflector|
    JP2017539589A| JP6810046B2|2015-01-28|2016-01-20|Thermoplastic material container sterilizer and method using pulsed electron beam and movable reflector|
    PCT/FR2016/050099| WO2016120544A1|2015-01-28|2016-01-20|Device and method for sterilizing thermoplastic containers using a pulsed electron beam and a mobile reflector|
    CN201680007378.1A| CN107206115B|2015-01-28|2016-01-20|Apparatus and method for sterilizing containers of thermoplastic material using pulsed electron beam and movable reflector|
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